Product ID:P-204 HAND-TUFF
MSDS Date:05/13/1992
FSC:5610
NIIN:00N065377
MSDS Number: CBCWP

PIONEER/RANDUSTRIAL

4529 INDUSTRIAL PARKWAY
CLEVELAND, OH 44135
US

Emergency Phone: 216-671-5500

Info Phone: 216-671-5500

Preparer: GEORGE SAJNER

Cage: 0VB04

PIONEER

CLEVELAND, OH 44135 US

Telephone: 216-671-5500

Cage: 0VB04

SILICATE, PORTLAND CEMENT; (PORTLAND CEMENT)

CAS: 65997-15-1

RTECS: VV8770000

Fraction By Weight: 30-50%

OSHA PEL 50 MPPCF; Z-3

ACGIH TLV: 10 MG/M3 TDUST

SILICA, CRYSTALLINE - QUARTZ;(SILICA SAND)

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: 49-69%

OSHA PEL SEE TABLE Z-3

ACGIH TLV: 0.1 MG/M3 RDUST

POLYMER PART CONSISTING OF INGREDIENTS 4 & 5.

RTECS: 9999999ZZ

ACRYLIC POLYMER

CAS: 25068-63-7

Fraction By Weight: 10-26%

OSHA PEL N/K

ACGIH TLV: N/K

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 74-90%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL: CHRONIC EXPOSURE MAY CAUSE
BRONCHITIS AND EMPHYSEMA. EYE: MAY CAUSE BURNING AND CORNEAL
DAMAGE. SKIN: MAY CAUSE IRRITATION, BURNS AND TISSUE DAMAGE.
INGEST: MAY CAUSE CAUSTIC BURNS IN THE MOUTH , ESOPHAGUS, STOMACH.
NOTE: CRYSTALLINEFREE SILICA HAS BEEN EVALUATED BY IARC AS HAVING
EVIDENCE OF (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC
MONOGRAPHS, SUPP. VOL 7, PG 341, 1987: GROUP 2A. NTP 7TH ANNUAL
REPORT ON(SUPDAT)
Effects of Overexposure:HLTH HAZ: PRODUCING CANCER IN LAB ANIMALS AND
LIMITED EVIDENCE IN HUMANS. NO DOCUMENTED CASES OF PNEUM OR OTHER
SYSTEMIC MANIFESTATIONS ATTRIBUTED TO FINISHED PORTLAND CEMENT
EXPOSURE HAVE BEEN REPORT ED.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:MOVE TO FRESH AIR. MONITOR FOR RESP DISTRESS. GIVE O*2
IF NEC. CALL MD/POIS CNTL CNTR IF SYMPS OCCUR. EYE:IRRIGATE EYE FOR
AT LEAST 15 MINS. IF PAIN, IRRIT/BURNING PERSISTS, CALL MD/POIS
CNTRL C NTR. INGEST: ADMIN MILK/WATER. DO NOT INDUCE VOM. CALL
MD/POIS CNTRL CNTR IMMED. DO NOT GIVE ANYTHING ORALLY TO AN UNCON
PERS. SKIN:WASH AREA TWICE W/SOAP & WATER. IF PAIN, IRRIT/BURNING
(SUPDAT)

Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:NONE. USE MEDIA SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:NONE.

Spill Release Procedures:SWEEP UP & DISPOSE OF IN STANDARD LANDFILL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:ALWAYS STORE MATERIAL ON PALLETS IN A
DRY LOCATION.
Other Precautions:ALL CHEMICALS SHOULD BE HANDLED SO AS TO PREVENT EYE
CONTACT AND EXCESSIVE OR REPEATED SKIN CONTACT. APPROPRIATE EYE AND
SKIN PROTECTION SHOULD BE EMPLOYED. INHALATION OF DUSTS AND VAPORS
SHOULD BE AV OIDED.

Respiratory Protection:A NIOSH/MSHA APPROVED DUST MASK PER 29CFR
1910.134.
Ventilation:ADEQUATE FRESH AIR.
Protective Gloves:RUBBERIZED GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS(SUPDAT)
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN: CARCINOGENS, 1994: ANITICPATED TO BE CARCINOGEN.
FIRST AID PROC: CALL MD/POIS CNTRL CTR. EYE PROT: & FULL LENGTH
FACESHIELD.

Spec Gravity:2.67-2.85
Appearance and Odor:GRAY W/NO ODOR.

Stability Indicator/Materials to Avoid:YES
WATER.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:NONE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL LAWS AND REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.